| Line 3: |
Line 3: |
| | This should be approachable by measuring 3 characteristics of LiOr solutions: | | This should be approachable by measuring 3 characteristics of LiOr solutions: |
| | | | |
| − | 1. conductance -- higher conductance implies free ions | + | 1. conductivity -- higher conductance implies free ions |
| | | | |
| | 2. osmolality -- higher osmolality implies dissociation | | 2. osmolality -- higher osmolality implies dissociation |
| Line 9: |
Line 9: |
| | 3. free Li+ concentration -- Li-selective electrode will detect Li+ if dissociated, but not in LiOr complex. | | 3. free Li+ concentration -- Li-selective electrode will detect Li+ if dissociated, but not in LiOr complex. |
| | | | |
| | + | ==Conductivity== |
| | + | |
| | + | From Aron 2025 et al: |
| | + | |
| | + | Conductivity measurements |
| | + | To measure the conductivity of Li salts, the salts were dissolved in water |
| | + | to achieve Li concentrations of 4.3 mEq l−1, 430 μEq l−1, 43 μEq l−1 or |
| | + | 21.5 μEq l−1 in each case. Conductivity was measured using an ST300C |
| | + | conductivity meter (OHAUS, 83033964) equipped with a STCON7 |
| | + | electrode (OHAUS, 30080693) calibrated with potassium chloride |
| | + | conductivity standards. For each lithium salt, three independent solu- |
| | + | tion replicates (n = 3) were prepared. Conductivity values are reported |
| | + | in μS per cm at 25 °C. |
| | | | |
| | ==Free Li+ Concentration== | | ==Free Li+ Concentration== |